Product ID:ETHYLENE GLYCOL TECH
MSDS Date:05/31/1989
FSC:6810
NIIN:00-006-4206
MSDS Number: BQLYQ

ASHLAND CHEMICAL COMPANY

COLUMBUS, OH 43216-2219
US

Emergency Phone: 800-274-5263

Info Phone: 614-889-3333

Cage: 34897

TEXAS INSTRUMENTS INC DEFENSE SYSTEM & ELECTRONICS

660246 DALLAS, TX 75266-0246 US

Telephone: 714-535-0646

Cage: 96214

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 100%

OSHA PEL C 50 PPM

ACGIH TLV: C 50 PPM,VAPOR; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:PEL=50PPM;TLV=50PPM (BOTH CEILING)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:IRRITANT.SKIN:SLIGHT
IRRITANT.INHAL:NASAL AND RESPIRATORY IRRITATION.INGEST:CAN CAUSE
GASTROINTESTINAL IRRITATION.CHRONIC EFFECTS ARE BIRTH
DEFECTS,KIDNEY AND LIVER DAMAGE AND CENTRAL NERVOUS SYS TEM
EFFECTS.
Explanation of Carcinogenicity:RTECS 92-4 SHOWS MONOGRAPHS ON ETHYLENE
GLYCOL AS A MUTAGEN,TUMORIGEN,REPRODUCTIVE EFFECTOR.
Effects of Overexposure:INGEST:NAUSEA,VOMITING,DIARRHEA.
Medical Cond Aggravated by Exposure:HMIS SUGGESTS THAT PERSONS WITH A
HISTORY OF KIDNEY OR LIVER DISORDERS MAYBE AT INCREASED RISK FROM
EXPOSURE.

First Aid:EYE:FLUSH W/ WATER 15 MIN HOLD LIDS OPEN. SKIN:REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF NECESSARY.
INGESTED:GIVE 2 GLASSES WATER AND INDUCE VOMITING(BYIPECAC OR
FINGER DOWN THROAT). GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET
IMMEDIATE MEDICAL CARE. IF IRRITATION PERSISTS,OR IS SEVERE,SEE A
DOCTOR.

Flash Point Method:TCC
Flash Point:232F,111C
Lower Limits:3.2
Upper Limits:15.3
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, OR WATER
FOG.WATER OR FOAM MAY CAUSE FROTHING.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAINERS ARE AN EXPLOSION HAZARD.

Spill Release Procedures:WIPE/SOAK UP WITH PAPER TOWEL OR INERT
ABSORBENT. PUT IN DISPOSAL CONTAINER. FLUSH RESIDUE WITH WATER.
LARGE SPILL: VENTILATE AREA. IF POSSIBLE, STOP LEAK. DIKE TO RETAIN
RUN OFF. VACUUM UP FREE LIQUI D. FLUSH RESIDUE WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:'EMPTY' CONTAINERS MAY CONTAIN RESIDUE OR VAPOR. DO
NOT PRESSURIZE,CUT,WELD,BRAZE,ETC. NEAR THEM.

Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC DUST/MIST IF EXPOSURE IS
ABOVE THE TLV/PEL. SEE 29 CFR 1910.134 FOR REGULATIONS PERTAINING
TO RESPIRATOR USE.
Ventilation:NORMAL VENTILATION IS USUALLY SUFFICIENT. SUPPLEMENT WITH
LOCAL EXHAUST IF PEL/TLV IS EXCEEDED.
Protective Gloves:NEOPRENE, NITRILE, PVC OR NATURAL RUBBER
Eye Protection:SAFETY GLASSES OR SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. AVOID
PROLONGED AND/OR REPEATED CONTACT BY USING APPROPRIATE CLOTHING.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. WASH THOROUGHLY BEFORE EATING OR DRINKING.
Supplemental Safety and Health
POISONOUS.

HCC:V5
Boiling Pt:=192.8C, 379.F
Vapor Pres:0.1
Vapor Density:2.2
Spec Gravity:1.115
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE = 1)
Solubility in Water:COMPLETE
Appearance and Odor:NOT REPORTED.HMIS SUGGESTS LIQUID;COLORLESS;NO
ODOR;SWEET TASTE.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE

Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER SUGGESTS THAT DISPOSAL MAY BE DONE BY
INCINERATION, AND THAT SMALL AMOUNTS CAN BE EVAPORATED UNDER A FUME
HOOD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.